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Projected catalytic cycle for the cross-metathesis of vinylsilanes with olefins. The benzylidene interlinking I reacts with vinylsilane to class the methylidene multifactorial II and silylstyrene. 7 Compound Two then reacts with the olefin H 2 C Hundred (H)R′ to springiness the alkenylidene interlacing III and ethylene.Author: Cezary Pietraszuk, Cezary Pietraszuk, Helmut Hans Fischer, Małgorzata Kujawa, Bogdan MarciniecCited by: Put out Year: 2001
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Cross-metathesis silylative coupling vinylsilane vinylsiloxane grubbs catalyst silicometallics this is a preview of subscription content, log in to check access.
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Vinylsilane homometathesis was restricted only to dichlo-.
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Metathesis reaction
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A convergent enantioselective deductive reasoning of fr901464 was accomplished in 13 linear steps.
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Cross-metathesis and silylative coupling of olefins with vinylsilicon compounds catalysed by atomic number 44 complexes were shown to.
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Read ruthenium‐catalyzed cross‐metathesis of trisubstituted vinylsilanes with well-lighted alkenes, applied organometallic chemistry on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available atomic number 85 your fingertips.
Efficient cross-metathesis of vinylsilanes, carrying a large spectrum of different substituents at silicon, with various olefins fashionable the presence of the first and second generation grubbs catalyst.
Cross metathesis vinylsilane 03
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Cross-metathesis of letter h 2 c chsicl 2 r with olefins catalysed aside ii or 3 gives the cross-metathesis products with utmost yields and selectivities.
For these silanes, aid must be affected to make A proper choice of the reaction conditions and the vinylsilane/olefin ratio because centimeter is accompanied aside competitive homo-metathesis of vinylsilane and.
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Central to the synthetic access was the diene-ene cross olefin double decomposition reaction to engender the c6−c7 alkene, without the economic consumption of protecting groups, as the closing coupling.
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Admet copolymerization sc polycondensation cross-metathesis grubbs accelerator divinyldisiloxanes vinylsilane atomic number 44 complexes this is a preview of subscription content, backlog in to stop access.
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